Dictionary Definition
fulminate n : a salt or ester of fulminic
acid
Verb
1 criticize severely; "He fulminated against the
Republicans' plan to cut Medicare"; "She railed against the bad
social policies" [syn: rail]
2 come on suddenly and intensely; "the disease
fulminated"
3 cause to explode violently and with loud
noise
User Contributed Dictionary
English
Etymology
fulminare, to strike like lightningPronunciation
- /fʌlˈmɪn.eɪt/ /fVl"mIn.eIt/ a UK
Noun
- Any salt or ester of fulminic acid; mostly explosive.
Verb
- To detonate or explode, or to cause something to detonate.
- intransitive figurative To make a verbal attack.
- transitive figurative To issue a denunciation.
Related terms
Italian
Verb
fulminate- Form of Second-person plural present tense, fulminare
- Form of Second-person plural imperative, fulminare#Italian|fulminare
Extensive Definition
Fulminates are chemical compounds
which include the fulminate ion. The fulminate ion is a pseudohalic ion, acting like a halogen with its charge and
reactivity. Due to the instability of the ion, they are friction-sensitive
explosives. The best
known is mercury
fulminate which has been used as a primary explosive in
detonators. Fulminates
can be formed from metals, like silver
and mercury,
dissolved in nitric acid and reacted with alcohol. The chemical formula
for the fulminate ion is
O−N+C−. It is largely
the presence of the weak single nitrogen-oxygen bond which leads to
its instability. Nitrogen very easily forms a stable triple bond
to another nitrogen atom, forming gaseous nitrogen.
Historical notes
Fulminates were discovered by Edward Charles Howard in 1800.. Their use in firearms in a fulminating powder was first demonstrated by a Scottish minister, A. J. Forsyth, who was granted a patent in 1807. Joshua Shaw then made the transition to their use in metallic encapsulations, to form a percussion cap, but did not patent his invention until 1822.In the 1820s, the organic chemist Justus
Liebig discovered silver
fulminate (Ag-CNO) and Friedrich
Wöhler discovered silver cyanate (Ag-NCO). The fact that
these substances have the same chemical
composition led to an acrid dispute, which was not resolved
until Jöns
Jakob Berzelius came up with the concept of isomers.
Compounds
- Silver fulminate
- Mercury(II) fulminate
- Fulminic acid
- Cyanate, has related OCN− structure
References
See also
fulminate in Croatian: Fulminati
fulminate in Portuguese: Fulminato